Effect of the Structural and Electrical Properties of Bi2-xPbxBa2Ca2Cu3O10+δ Superconductors with Partial Substitution of Lead by Bismuth
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Abstract
This manuscript discusses the preparation of Bi2-xPbxBa2Ca2Cu3O10+δ compounds by the method of solid-state reaction at the annealing temperature 850 C˚. Under pressure of 8ton/cm2 with a presence of enough oxygen and these are considered as ideal conditions according to the previous researches in the preparation of electric superconductors of high degree temperatures the effect of partial substitution was on Lead )Pb( e1ement in the Bismuth (Bi) e1ement was studied to produce a compound with formula of Bi2-xPbxBa2Ca2Cu3O10+δ and for different ratios of x to know the effect of partial substitution to form Bi2223 phase at the annealing time 72 hrs and we concluded from study of diffraction of x-ray that the compound kept its tetragonal structure , and critical temperature)Tc( degrees were obtained Tc= 128K,130K, 135K, 132K, and that’s at substitution ratios x=0,0.15,0.25,0.3, respectively it was clear the best substitution ratios of pb in Bi was when x=0.25.
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